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Coloured Glass

   Here,s a little bit of info about the chemicals used to colour glass,for further reading take a look at bottle collecting by E.Fletcher.(sadly out of print,but may turn up at second hand book stalls ect)or your local library may be able to help.


 The early glass makers were really not that bothered about the quality of thier glass,the iron oxide in the sand they used produced a light green glass which ideally suited the wine bottles they were producing.But as demand for goods packaged in glass increased manufacturers began to demand darker colours(often to disguise impurities in the contents,ie sediment in beer or wine).To accomodate these wishes the makers added more iron oxide to the melt to produce dark green glass.Even larger ammounts made brown glass(often used for early medicines,poisons).Even darker brown(or black glass)was produced by adding small ammounts of coal or charcoal as well as the iron oxide.Blue glass often used for later poisons and medicines was produced by adding cobalt(dark blue)or copper oxide(lighter blue).It is likely that the copper oxide was of most use to the glassmaker as by varying both the ammount used and the temperature of the melt blue,light red or emerald green glass could be produced.Milk glass(white) was popular (and still is) for creams and other cosmetics and was made by adding either tin or zinc oxide to the melt.Small ammounts of either sulpher,silver or chromium produced varying shades of yellow(also popular for cosmetics/perfumes.Ruby or red glass was made by adding 1oz of gold to 60lbs of glass.Consequently it is very rare to find a commercial bottle in ruby glass.(due to the expense).These days ruby glass is made by adding selenium to the melt.Clear glass became more popular from the start of the 20th centuary and was produced by adding manganese.(an added benefit/hindrance to this is that early clear glass can often be subjected to ultra violet light to produce a light purple colour bottle/or cooked to make a fairly common bottle a bargain(expensive buy) for the novice collector,of which I am one,I havnt bought a purple bottle yet though.From the 1920s on selenium replaced manganese,these bottles are unaffected by UV light.Though in very VERY hot climates they have been known to turn a very pale yellow if the glass contains large ammounts of selenium.


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